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ChemInform Abstract: Negishi Alkyl—Aryl Cross-Coupling Catalyzed by Rh: Efficiency of Novel Tripodal 3-Diphenylphosphino-2-(diphenylphosphino)methyl-2-methylpropyl Acetate Ligand.

✍ Scribed by Syogo Ejiri; Shunsuke Odo; Hideki Takahashi; Yugo Nishimura; Kazuma Gotoh; Yasushi Nishihara; Kentaro Takagi

Publisher: John Wiley and Sons
Year: 2010
Weight: 68 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201034051

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✦ Synopsis

Abstract

The reaction is effective for the aromatic zinc derivatives bearing electron‐withdrawing substituents, while poor yields are observed for the electron‐donating and unsubstituted substrates [cf.

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