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ChemInform Abstract: Na1.5Ag1.5MO3F3 (M: Mo, W): An Ordered Oxyfluoride Derivative of the LiNbO3 Structure.

✍ Scribed by Allyson M. Fry; Harry A. II Seibel; Indunil N. Lokuhewa; Patrick M. Woodward


Book ID
112045556
Publisher
John Wiley and Sons
Year
2012
Weight
22 KB
Volume
43
Category
Article
ISSN
0931-7597

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## Abstract Reaction of [(Ξ·^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the Ξ·^3^‐1,2‐diphosphaallyl complexes [(Ξ·^5^‐C~5~H~5~)(CO)~2~M{Ξ·^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C