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ChemInform Abstract: N-Trityl- and N-Phenylfluorenyl-N-carboxyanhydrides and Their Use in Dipeptide Synthesis.

✍ Scribed by Tae Bo Sim; Henry Rapoport

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

N-Trityl-and N-Phenylfluorenyl-N-carboxyanhydrides and Their Use in Dipeptide Synthesis.

-Heating of title compounds like (IV) and (XI) with amino acids in THF leads to dipeptides in good yields with complete enantiomeric integrity. In the presence of KCN as well as NaN 3 significant epimerization takes place. -(SIM,

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