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ChemInform Abstract: N-Heterocyclic Carbene-Mediated Organocatalytic Transfer of Tin onto Aldehydes: New Access to α-Silyloxyalkylstannanes and γ-Silyloxyallylstannanes.

✍ Scribed by Romain Blanc; Laurent Commeiras; Jean-Luc Parrain

Publisher
John Wiley and Sons
Year
2010
Weight
52 KB
Volume
41
Category
Article
ISSN
0931-7597

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N-Heterocyclic Carbene-Mediated Organoca
N-Heterocyclic Carbene-Mediated Organocatalytic Transfer of Tin onto Aldehydes: New Access to α-Silyloxyalkylstannanes and γ-Silyloxyallylstannanes
✍ Romain Blanc; Laurent Commeiras; Jean-Luc Parrain 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 207 KB

## Abstract A new, highly efficient and mild N‐heterocyclic carbene (NHC)‐mediated organocatalytic procedure for the transfer of tin from tributyl(trimethylsilyl)stannane (Bu~3~SnSiMe~3~) onto aldehydes for the preparation of α‐silyloxyalkylstannanes and γ‐silyloxyallylstannanes has been developed.