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ChemInform Abstract: N-Heterocyclic Carbene Catalyzed Reaction of Phthalaldehydes: Controllable Stereoselective Synthesis of Polyhydroxylated Spiro- and Fused Indenones Dictated by the Structure of NHC Catalysts.

✍ Scribed by Ying Cheng; Jiang-Hua Peng; Yong-Jia Li; Xun-Yu Shi; Ming-Sheng Tang; Tian-Yu Tan


Publisher
John Wiley and Sons
Year
2011
Weight
43 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

In the presence of IMC, phthalaldehydes undergo efficient dimerization yielding spirocyclic indenones like (II).