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ChemInform Abstract: N-Allyl-N-sulfonyl Ynamides as Synthetic Precursors to Amidines and Vinylogous Amidines. An Unexpected N-to-C 1,3-Sulfonyl Shift in Nitrile Synthesis.

✍ Scribed by Kyle A. DeKorver; Whitney L. Johnson; Yu Zhang; Richard P. Hsung; Huifang Dai; Jun Deng; Andrew G. Lohse; Yan-Shi Zhang


Publisher
John Wiley and Sons
Year
2011
Weight
80 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The Pd‐catalyzed or thermally‐induced treatment of ynamides of type (I) with amines allows convenient access to amidines.