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ChemInform Abstract: N-Alkylation of Diaziridines.

โœ Scribed by Nina N. Makhova; Gennadii A. Karpov; Anatolii N. Mikhailyuk; Lenor I. Khmel'nitskii


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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For the first time the nitrogen inversion barriers in 3,3-unsubstituted trans-diaziridines, such as 1,2-di-tert-butyldiaziridine (1) and 1,2-di-n-butyldiaziridine (2) were determined. Enantioselective stopped-flow multidimensional gas chromatography was used to investigate the enantiomerization barr