ChemInform Abstract: Morita—Baylis—Hillman Adducts as Effective Dipolarophiles in Copper(I)-Catalyzed 1,3-Dipolar Cycloaddition with Azomethine Ylides: Asymmetric Construction of Pyrrolidine Derivatives Containing Quaternary Stereogenic Center.

✍ Scribed by Huai-Long Teng; He Huang; Hai-Yan Tao; Chun-Jiang Wang

• Publisher: John Wiley and Sons
• Year: 2011
• Weight: 33 KB
• Volume: 42
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201137027

✦ Synopsis

Abstract

The first catalytic asymmetric 1,3‐dipolar cycloaddition of azomethine ylides (II) with Morita—Baylis—Hillman adducts bearing an allylic hydroxyl group is described.