Molecular switches: Calculations on the
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Tietze, Lutz F. ;Schulz, Gerhard
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Article
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1995
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John Wiley and Sons
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English
β 375 KB
## Abstract The stereodivergent facial differentiation of the intermolecular hetero DielsβAlder reaction of the 1βoxaβ1,3βbutadiene 1 with 2 in the presence of trimethylsilyl trifluoromethanesulfonate (TMSβOTf) or Me~2~AlCl is explained on the basis of semiempirical calculations (AM1 and PM3). The