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ChemInform Abstract: Molecular Switches: Calculations on the Stereodivergent Hetero Diels- Alder Reaction of Chiral 1-Oxa-1,3-butadienes with Different Lewis Acids.

✍ Scribed by L. F. TIETZE; G. SCHULZ


Book ID
112027491
Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
27
Category
Article
ISSN
0931-7597

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Molecular switches: Calculations on the
✍ Tietze, Lutz F. ;Schulz, Gerhard πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 375 KB

## Abstract The stereodivergent facial differentiation of the intermolecular hetero Diels‐Alder reaction of the 1‐oxa‐1,3‐butadiene 1 with 2 in the presence of trimethylsilyl trifluoromethanesulfonate (TMS‐OTf) or Me~2~AlCl is explained on the basis of semiempirical calculations (AM1 and PM3). The