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ChemInform Abstract: Molecular Rearrangements of α-(trans)- and β-(cis)-3,4-Epoxycaranes in Acidic Media.

✍ Scribed by M. P. POLOVINKA; D. V. KORCHAGINA; YU. V. GATILOV; O. G. VYGLAZOV; G. A. ZENKOVETS; V. A. BARKHASH


Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
30
Category
Article
ISSN
0931-7597

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Pyroglutamic acid derivative (I) is proved to be an excellent chiral starting compound for the synthesis of title amino acids (IX), (X), and (V). The syntheses are based on a combination of methods previously used for the preparation of 4-and 5-substituted prolines. These methods are the ring openin