ChemInform Abstract: Molecular Orbital Study of the Rearrangement of Seleniranium Ions
β Scribed by Z. MARKOVIC; S. KONSTANTINOVIC; I. JURANIC; L. DOSEN-MICOVIC
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 24 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Molecular Orbital Study of the Rearrangement of Seleniranium Ions -[mechanism of phenylselenoetherification of unsaturated alcohols involving seleniranium cationic intermediates].
-(MARKOVIC, Z.; KONSTANTI-
π SIMILAR VOLUMES
## Abstract CNDO/Z, MINDO/3 and __ab initio__ molecular orbital calculations indicate that Cβprotonated diazomethane is more stable than N(end)βprotonated diazomethane. Extrapolation of these results to solution chemistry as well as the kinetic references of protonation of diazomethane are discusse
## Abstract Review: 47 refs.