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ChemInform Abstract: Modification of Organotin Hydrides for Chemo-, Stereo- and Regiocontrolled Reductions

✍ Scribed by I. SHIBATA; A. BABA

Publisher: John Wiley and Sons
Year: 2010
Weight: 25 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199835334

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A New Halogen-Exchange Reaction Between Sn-F and Li-X: Selective 1,2-and 1,4-Reductions of α,β-Unsaturated Ketones and Effects of Halogen Substituents on the Regioselectivity of Organotin Hydrides. -In dependence of the additive a highly regioselective reduction is obtained under optimized condition