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ChemInform Abstract: Model Studies of the Overall 5-endo-trig Iodocyclization of Homoallylic Alcohols.

✍ Scribed by Simon B. Bedford; Kathryn E. Bell; Frank Bennett; Christopher J. Hayes; David W. Knight; Duncan E. Shaw

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199944119

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✦ Synopsis

Model Studies of the Overall 5-endo-trig Iodocyclization of Homoallylic Alcohols.

-The title reaction proceeds efficiently and stereoselectively in anhydrous MeCN. The iodine in products (II) can be replaced by hydroxy, acetoxy or azide groups [cf. furan derivative (VII)]. -

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