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ChemInform Abstract: Mixed-Ligand Hydroxohydroperoxide Tin(IV) Complexes.

✍ Scribed by E. G. Ippolitov; L. S. Skogareva; T. A. Tripol'skaya


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Mixed-Ligand Hydroxohydroperoxide Tin(IV) Complexes.

-Mixed sodium hydroxyhydroperoxostannates such as Na

and Na 2 [Sn(OH) 3 (OOH) 3 ] (III) are synthesized and characterized by IR-and X-ray analyses. Complex (I) possesses the same structure as the octahedral complex Na[Sn(OOH) 6 ], complex (II) is amorphous, and complex (III) appears to be a mixture of complexes (I) and (II). -(IPPOLITOV, E.


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## Abstract The reduction of 4,6‐di‐tert‐butyl‐N‐(2, 6‐di‐iso‐propylphenyl)‐o‐iminobenzoquinone (imQ) by tin amalgam in hexane solution leads to new six‐coordinated o‐iminoquinonato tin(IV) complex (iSQ)~2~SnAP (**1**) (where iSQ and AP are o‐iminosemiquinolate and dianion o‐amidophenolate, respect