ChemInform Abstract: Mixed Alkali Oxidosulfidomolybdates A2[MoOxS4-x] (x = 1, 2, 3; A: K, Rb, Cs, NH4). Synthesis, Crystal Structure and Properties.
β Scribed by Anna J. Lehner; Korina Kraut; Caroline Roehr
- Book ID
- 112045555
- Publisher
- John Wiley and Sons
- Year
- 2012
- Weight
- 23 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
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Treatment of A 2 CO 3 (A β«Ψβ¬ K, Rb) with Sn and Se in an H 2 O/CH 3 OH mixture at 1303C a4ords reaction solutions from which respectively K 4 Sn 4 Se 10 ' 4.5H 2 O (1) and Rb 4 Sn 4 Se 10 ' 1.5H 2 O (2) can be isolated on cooling. 1 crystallizes in the rhombohedral space group R3 with a β«Ψβ¬ b β«Ψβ¬ 15