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ChemInform Abstract: Microbiological Synthesis of 17β-Hydroxyandrosta-1,4-dien-3-one.

✍ Scribed by E. V. Popova; K. N. Gabinskaya; S. D. Shuvalova; S. A. Dovzhenko; V. A. Andryushina

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
32
Category
Article
ISSN
0931-7597

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New Synthesis of Estradiol from Androsta-1,4-diene-3,17-dione. -A new method for the aromatization of ring A in androsta-1,4-diene-3,17-dione (I) via reduction to the corresponding dienediol (II) followed by double C,Odeprotonation of ring A is reported. This two-step transformation of (I) into est