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ChemInform Abstract: Michael Addition Initiated Carbocyclization Sequences with Nitroolefins for the Stereoselective Synthesis of Functionalized Heterocyclic and Carbocyclic Systems.

✍ Scribed by Estelle Dumez; Anne-Catherine Durand; Martial Guillaume; Pierre-Yves Roger; Robert Faure; Jean-Marc Pons; Gaetan Herbette; Jean-Pierre Dulcere; Damien Bonne; Jean Rodriguez

Publisher: John Wiley and Sons
Year: 2010
Weight: 65 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201010034

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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Strategy for the Construction of Functionalized Five-and Six-Membered Carbocycles. -Conjugate addition of the Grignard reagents (II) and (IV) to the nitro olefins (I) leads to the intermediate formation of nitronates, which are trapped as silyl nitronates and subsequently cyclized by intramolecular