𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Methyllithium-Promoted Wittig Rearrangements of α-Alkoxysilanes.

✍ Scribed by Robert E. Maleczka Jr.; Feng Geng

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
30
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

ChemInform Abstract: Organoaluminum-Prom
ChemInform Abstract: Organoaluminum-Promoted Rearrangement of Epoxysilanes to α- Silylaldehydes.
✍ T. OOI; T. KIBA; K. MARUOKA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

Organoaluminum-Promoted Rearrangement of Epoxysilanes to α-Silylaldehydes. -Selective rearrangement of epoxysilanes to αsilylaldehydes is achieved with high efficiency by using the exceptionally bulky Lewis acid MABR as s stoichiometric reagent. Rearrangement of deuterated derivatives (III) and (V)

ChemInform Abstract: Synthesis of α-Alko
ChemInform Abstract: Synthesis of α-Alkoxysilanes: Birch Reduction of 2- Trialkylsilylfurans.
✍ R. L. BEDDOES; M. L. LEWIS; P. GILBERT; P. QUAYLE; S. P. THOMPSON; S. WANG; K. M 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB

Synthesis of α-Alkoxysilanes: Birch Reduction of 2-Trialkylsilylfurans. -Birch reduction of 2-silylfuran-3-carboxylic acids such as (I) results in diastereoselective formation of the trans products after diazomethane esterification and final catalytic hydrogenation. The silyl substituent of (IIIa)