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ChemInform Abstract: Methyl 3,3-Bis(trialkylstannyl)acrylates: An Improved Preparative Procedure.

✍ Scribed by P. QUAYLE; J. WANG; J. XU; C. J. URCH

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Methyl 3,3-Bis(trialkylstannyl)acrylates: An Improved Preparative Procedure. -Hydrostannylation of the stannylpropiolate (I) under radical conditions yields the 3,3-bis(tributylstannyl)acrylate (III). In comparison the Pd-catalyzed hydrostannylation proceeds in a regioinversed manner affording the vinylstannanes (IV) and (V). -(QUAYLE, P.;

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