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ChemInform Abstract: Metal—Organic Frameworks as Efficient Heterogeneous Catalysts for the Regioselective Ring Opening of Epoxides.

✍ Scribed by Amarajothi Dhakshinamoorthy; Mercedes Alvaro; Hermenegildo Garcia

Publisher: John Wiley and Sons
Year: 2010
Weight: 36 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201052030

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✦ Synopsis

Abstract

The iron‐based metal—organic framework IBTC efficiently catalyzes the ring opening of epoxides with alcohols under mild heterogeneous conditions.

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## Abstract An iron‐based metal–organic framework, [Fe(BTC)] (BTC: 1,3,5‐benzenetricarboxylate) is an efficient catalyst in the ring opening of styrene oxide with alcohols and aniline under mild reaction conditions. Out of the various alcohols tested for ring opening of styrene oxide, methanol was

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## Abstract Review: 91 refs.

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ChemInform Abstract: Metal-Organic Frameworks (MOFs) as Heterogeneous Catalysts for the Chemoselective Reduction of Carbon—Carbon Multiple Bonds with Hydrazine.

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