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ChemInform Abstract: Metalated Nitriles: Internal 1,3-Asymmetric Induction.

✍ Scribed by Fraser F. Fleming; Wang Liu

Book ID
102034906
Publisher
John Wiley and Sons
Year
2009
Weight
52 KB
Volume
40
Category
Article
ISSN
0931-7597

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

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## Abstract Stereoselective alkylations of acyclic, metalated nitriles are intimately controlled by a remote stereocenter. Probing the optimal steric demand through alkylations with a series of substituted pentanenitriles reveal the fundamental requirements for 1,3‐asymmetric induction. Relaying th