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ChemInform Abstract: Metal-Template ortho-Regioselective Synthesis of 2′- Hydroxyphenylpyridinemethanols.

✍ Scribed by G. SARTORI; R. MAGGI; F. BIGI; A. ARIENTI; C. PORTA; G. PREDIERI

Book ID
112021135
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
26
Category
Article
ISSN
0931-7597

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Regioselective Directed ortho Metalation of 3H-Naphtho[2,1b]pyrans. Synthesis of Methylteretifolione B. -Treatment of naphthopyrans with tBuLi under controlled conditions results in selective ortho-metalation. Following quenching with electrophiles yields single products. The methyl derivative (II