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ChemInform Abstract: Metal-Centered Deltahedral Zintl Ions: Synthesis of [Ni@Sn9]4- by Direct Extraction from Intermetallic Precursors and of the Vertex-Fused Dimer [{Ni@Sn8(μ-Ge)1/2}2]4-.

✍ Scribed by Miriam M. Gillett-Kunnath; Joseph I. Paik; Sara M. Jensen; Jacob D. Taylor; Slavi C. Sevov


Publisher
John Wiley and Sons
Year
2012
Weight
36 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The endohedral cluster [Ni@Sn~9~]^4‐^ is extracted in en from the new precursors (I), (IV), and (VII), which are obtained from mixtures of the elements (Nb containers, 950 °C, 2 d).