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ChemInform Abstract: Metal-Catalyzed Reactions of Alkynes. Part 2. Palladium-Catalyzed Trimerizations of Terminal Arylalkynes: Synthesis of 1,3-Diaryl-2-arylethynyl-1,3-butadienes.

✍ Scribed by Yao-Ting Wu; Wei-Chih Lin; Chia-Ju Liu; Chuan-Yi Wu


Publisher
John Wiley and Sons
Year
2008
Weight
58 KB
Volume
39
Category
Article
ISSN
0931-7597

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## Abstract Various 1,3‐diaryl‐2‐arylethynyl‐1,3‐butadienes **7** have been prepared by the Pd‐catalyzed trimerization of arylalkynes **4**. Their structures and stereochemistry have been confirmed by X‐ray crystal analyses. This procedure provides high regioselectivity to generate adducts __Z__‐**

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