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ChemInform Abstract: Metal-Catalyzed Living Radical Polymerization

✍ Scribed by Masami Kamigaito; Tsuyoshi Ando; Mitsuo Sawamoto


Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
33
Category
Article
ISSN
0931-7597

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Quenching of metal-catalyzed living radi
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Various silyl enol ethers were employed as quenchers for the living radical polymerization of methyl methacrylate with the ROCl/RuCl 2 (PPh 3 ) 3 /Al(Oi-Pr) 3 initiating system. The most effective quencher was a silyl enol ether with an electrondonating phenyl group conjugated with its double bond [