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ChemInform Abstract: Mechanistic Switch via Subtle Ligand Modulation: Palladium-Catalyzed Synthesis of α,β-Substituted Styrenes via C—H Bond Functionalization.

✍ Scribed by Areli Flores-Gaspar; Ruben Martin

Publisher: John Wiley and Sons
Year: 2011
Weight: 63 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201139041

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✦ Synopsis

Abstract

It is found that Pd‐catalyzed treatment of 2‐(2‐bromoaryl)propanals can lead to benzocyclobutenones and/or substituted styrenes depending on the phosphine ligand used.

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