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ChemInform Abstract: Mechanistic Studies in the Radical Induced DNA Strand Cleavage — Formation and Reactivity of the Radical Cation Intermediate.

✍ Scribed by Ralf Glatthar; Martin Spichty; Andreas Gugger; Rohit Batra; Wolfgang Damm; Matthias Mohr; Hendrik Zipse; Bernd Giese


Publisher
John Wiley and Sons
Year
2000
Weight
25 KB
Volume
31
Category
Article
ISSN
0931-7597

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✍ Woon Ju Song; Ying Ji Sun; Sun Kyung Choi; Wonwoo Nam 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 319 KB

## Abstract We have shown previously that iodosylbenzene–iron(III) porphyrin intermediates (2) are generated in the reactions of oxoiron(IV) porphyrin π‐cation radicals (1) and iodobenzene (PhI), that 1 and 2 are at equilibrium in the presence of PhI, and that the epoxidation of olefins by 2 afford