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ChemInform Abstract: Mechanism and Application of the Newman—Kwart O→S Rearrangement of O-Aryl Thiocarbamates

✍ Scribed by Guy C. Lloyd-Jones; Jonathan D. Moseley; Joseph S. Renny


Book ID
102019605
Publisher
John Wiley and Sons
Year
2008
Weight
16 KB
Volume
39
Category
Article
ISSN
0931-7597

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Thermally induced O Ar !S Ar migration in aryl thiocarbamates (1!2, Scheme 1) [1] is commonly referred to [2] as the Newman-Kwart rearrangement ("NKR") [3] and belongs to a group of rearrangements that generate Ar-S/N compounds from phenols. [4] Of these, only the NKR has been extensively utilized,

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