Mapping the Mechanism of Nickel-Ferrophi
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Andrew Novak; Maria José Calhorda; Paulo Jorge Costa; Simon Woodward
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Article
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2009
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John Wiley and Sons
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English
⚖ 390 KB
## Abstract Enantioselective Ni‐catalysed methylation of Baylis–Hillman‐derived allylic electrophiles in the presence of ferrophite ligands has been investigated computationally and experimentally. The sense and degree of enantioselectivity attained is independent of both the leaving group and the