ChemInform Abstract: Magnesium Metal Mediated Reductive Trifluoromethylation of Aldehydes with Phenyl Trifluoromethyl Sulfone.
β Scribed by Yanchuan Zhao; Jieming Zhu; Chuanfa Ni; Jinbo Hu
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 20 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
The method is suitable for enolizable and nonβenolizable aldehydes via formation of a CF~3~^β^ species.
π SIMILAR VOLUMES
Cesium Fluoride Catalyzed Trifluoromethylation of Esters, Aldehydes, and Ketones with (Trifluoromethyl)trimethylsilane. -The title reaction is successfully applied to carboxylic, sulfonic, sulfinic, and selenic esters, and also to aldehydes and ketones, among them substrates that have been reported
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