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ChemInform Abstract: Magnesium Iodide Promoted Defluorinative Reactions of 2,2-Difluorocyclopropyl Aryl Ketones with Aryl Imines: A New, General Synthesis of 2-Alkylideneazetidines.

✍ Scribed by Wei Xu; Ion Ghiviriga; Qing-Yun Chen; William R. Dolbier


Publisher
John Wiley and Sons
Year
2010
Weight
22 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

Upon treatment with anhydrous MgI~2~, 2,2‐difluorocyclopropyl aryl ketones undergo an unexpected and unprecedented ring opening process leading to complete loss of fluorine.


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✍ Veejendra K. Yadav; Archana Gupta πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons βš– 31 KB

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