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ChemInform Abstract: Lithium Enediolates and Dienediolates of Carboxylic Acids in Synthesis: Alkylation with Secondary Halides.

โœ Scribed by Eva M. Brun; Salvador Gil; Ramon Mestres; Margarita Parra


Publisher
John Wiley and Sons
Year
2010
Weight
41 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enediolates and Die
โœ E. M. BRUN; S. GIL; R. MESTRES; M. PARRA; F. VILLAR ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 40 KB ๐Ÿ‘ 1 views

Enediolates and Dienediolates of Carboxylic Acids in Synthesis. Synthesis of ฮฒ,ฮณ-Epoxyacids from ฮฑ-Chloroketones. -Lithium dienolates of saturated acids (I) and (XII) react with ฮฑ-chloroketones to produce highly substituted ฮฒ,ฮณ-epoxyacids as the major products in most cases. Unsaturated acids such a