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ChemInform Abstract: Ligand-Controlled Enantioselective [2 + 2] Cycloaddition of Oxabicyclic Alkenes with Terminal Alkynes Using Chiral Iridium Catalysts.

✍ Scribed by Bao-Min Fan; Xiao-Jiao Li; Fang-Zhi Peng; Hong-Bin Zhang; Albert S. C. Chan; Zhi-Hui Shao


Publisher
John Wiley and Sons
Year
2010
Weight
40 KB
Volume
41
Category
Article
ISSN
0931-7597

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Reaction of 2-Hydroxybenzaldehydes with Alkynes, Alkenes, or Allenes via Cleavage of the Aldehyde C-H Bond Using a Rhodium Catalyst System. -Aldehyde (I) smoothly reacts with internal and terminal alkynes to give alkenoylphenols in good to excellent yields. The substituents of acetylene influence th