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ChemInform Abstract: Lewis Acid Catalyzed Intramolecular Amination via 1,3-Chirality Transfer.

✍ Scribed by Nobuyuki Kawai; Ryuzou Abe; Jun'ichi Uenishi

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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Synthesis of Chiral 1-Substituted Tetrahydroisoquinolines by the Intramolecular 1,3-Chirality Transfer Reaction Catalyzed by Bi(OTf)3. -Treatment of chiral amines of type (I), (III), and (V) with Bi(OTf)3 results in formation of optically active tetrahydroisoquinolines. The (E)/(Z) configuration of