✦ LIBER ✦
ChemInform Abstract: Large-Scale Preparation of Aromatic Fluorides via Electrophilic Fluorination with Functionalized Aryl- or Heteroarylmagnesium Reagents.
✍ Scribed by Shigeyuki Yamada; Paul Knochel
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 27 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
Grignard reagents, prepared either by halogen—magnesium exchange or direct magnesium insertion in the presence of LiCl, are treated with N‐fluorobenzenesulfonamide to afford the corresponding aromatic fluorides.