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ChemInform Abstract: Lanthanide Triflate-Catalyzed Three-Component Coupling Reactions of Aldehydes, Hydroxylamines, and Alkenes Leading to Isoxazolidine Derivatives.

✍ Scribed by S. KOBAYASHI; R. AKIYAMA; M. KAWAMURA; H. ISHITANI

Publisher: John Wiley and Sons
Year: 2010
Weight: 39 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199805126

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Preparation of Substituted Alkylpyrroles via Samarium-Catalyzed Three-Component Coupling Reaction of Aldehydes, Amines, and Nitroalkanes. -Pyrroles of type (IV) are prepared from saturated aldehydes in the presence of a catalytic amount SmCl 3 under mild conditions. If α,β-unsaturated aldehydes or