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ChemInform Abstract: L-Selectride as a General Reagent for the O-Demethylation and N-Decarbomethoxylation of Opium Alkaloids and Derivatives.

✍ Scribed by A. COOP; J. W. JANETKA; J. W. LEWIS; K. C. RICE

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

L-Selectride as a General Reagent for the O-Demethylation and N-Decarbomethoxylation of Opium Alkaloids and Derivatives.

-L-Selectride is shown to be an efficient O-demethylating reagent for the opium alkaloids and an efficient reagent for the cleavage of methyl carbamates, thus offering a convenient method for the N-demethylation of opioids. Furthermore, controlled N-decarbomethoxylation can be carried out with or without accompanying O-demethylation. -(COOP, A.;

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