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ChemInform Abstract: Kinetics of the Enolization Reactions of 3-Acetyl-2,5-dimethylfuran and of 2-Acetylselenophene.

✍ Scribed by P. DE MARIA; A. FONTANA; G. SIANI; D. SPINELLI

Publisher: John Wiley and Sons
Year: 2010
Weight: 24 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199849032

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Rate constants for the enolisation reactions of title reactivities in the acid-catalysed reactions. Brønsted β values and isotope effects, k H /k D , point to a more symmetrical compounds have been measured by their rates of halogenation at 25 °C in water, in several buffers, in dilute transition st

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

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## Abstract The synthesis of two diastereomers of the title compound involves the coupling of 5‐lithiated 2‐(1,1‐dimethoxyethyl)thiazole (VI) with a Weinreb amide (V) derived from gluconolacetone, followed by asymmetric reduction of the ketone functionality.