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ChemInform Abstract: Kinetics and Mechanism of the Hydrolysis of N-(4-Chlorobenzoyl)-C-(5-methyl-1,3,4-thiadiazol-2-thio)imidoyl Chloride (I).

✍ Scribed by K.-S. KWON; J.-N. HEO; C. KIM; Y.-G. LEE; N.-D. SUNG


Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
29
Category
Article
ISSN
0931-7597

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Kinetics of the hydrolysis of cyclic N-s
✍ M. F. Rozas; E. L. Svartman; M. V. MirΓ­fico; E. J. Vasini πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 150 KB πŸ‘ 2 views

The hydrolysis reactions of 4-amino-2-phenethyl-and 4-amino-2-cyclohexyl-2,3-dihydro-3-oxo-1,2,5thiadiazole 1,1-dioxide (Ia and Ib) were investigated in the range 24-73 Β°C in buffered aqueous solutions. The observed rate constants (k obs ) are independent of pH in the range ca 1-4 pH, but increase w