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ChemInform Abstract: KGaAs2O7.

✍ Scribed by K.-J. LIN; K.-H. LII


Publisher
John Wiley and Sons
Year
2010
Weight
23 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


1997 structure structure (solids and liquids) D 2000

05 -006

KGaAs2O7.

-Single crystals of the title compound are obtained from the reation of KH2AsO4, (NH4)H2AsO4, and Ga2O3 (Pt crucible, 1. 773 K, 6 h, 2. 973 K, 10 h). KGaAs2O7 crystallizes in the triclinic space group P1 with Z = 2. The compound is isostructural with KAlAs2O7. Corner-sharing GaO6 octahedra and As2O7 double tetrahedra form tunnels in which two crystallographically independent K+ ions are located. -(LIN, K.-


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