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ChemInform Abstract: Isotopic Desymmetrization as a Stereochemical Probe

✍ Scribed by Guy C. Lloyd-Jones

Publisher
John Wiley and Sons
Year
2001
Weight
23 KB
Volume
32
Category
Article
ISSN
0931-7597

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The -C NMR spectra of tertiary fluorinated steroids possessing no functional groups in the vicinity of the fluorine have been measured. All a-and @-carbons are deshielded by the fluorine atom. The y-carhons, however, are divided into two groups. The carbons gauche to the fluorine atom are all shield