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ChemInform Abstract: Isothiocyanate Reactions with Organometallic Compounds. Part 2. Carbanions of Vinyl Ethers, Vinyl Sulfides, and Cycloalkenes in Reaction with Isothiocyanates. Synthesis of 2-Propen-1-imines, Methanimines, and Thiazole Derivatives.

✍ Scribed by L. Brandsma; N. A. Nedolya; V. P. Zinov'eva; G. I. Sarapulova; B. A. Trofimov

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199951047

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✦ Synopsis

Isothiocyanate Reactions with Organometallic Compounds. Part 2. Carbanions of Vinyl Ethers, Vinyl Sulfides, and Cycloalkenes in Reaction with Isothiocyanates. Synthesis of 2-Propen-1-imines, Methanimines, and Thiazole Derivatives.

-Reactions of carbanions, produced in situ by the action of superbases on the title vinyl compounds, with various isothiocyanates followed by alkylation of the formed thiolate intermediates are described.

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