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ChemInform Abstract: Isonitrile-Nitrile Rearrangement Promoted by Samarium(II) Iodide.

✍ Scribed by H.-Y. KANG; A. N. PAE; Y. S. CHO; H. Y. KOH; B. Y. CHUNG

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Intramolecular Keto
ChemInform Abstract: Intramolecular Ketoneβ€”Nitrile Reductive Coupling Reactions Promoted by Samarium(II) Iodide.
✍ Gary A. Molander; Chad N. Wolfe πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 37 KB πŸ‘ 2 views

Intramolecular Ketone-Nitrile Reductive Coupling Reactions Promoted by Samarium(II) Iodide. -The photochemically induced reaction of keto nitriles of type (I), (III), and (V) with SmI 2 offers an efficient route to prepare monocyclic, fused bicyclic, and bridged Ξ±-hydroxy ketones. 5-exo-Coupling pr