ChemInform Abstract: Iron-Catalyzed Sulfonyl Radical Formations from Sulfonylhydrazides and Oxidative Addition to Alkenes.

✍ Scribed by Tsuyoshi Taniguchi; Atsushi Idota; Hiroyuki Ishibashi

• Publisher: John Wiley and Sons
• Year: 2011
• Weight: 42 KB
• Volume: 42
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201134079

✦ Synopsis

Abstract

Sulfonyl radicals, generated by Fe‐catalyzed reaction of sulfonylhydrazides with air oxygen, add to a wide variety of olefins to give the corresponding β‐hydroxysulfones in moderate to good yields.