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ChemInform Abstract: Iron-Catalyzed Chemoselective Cross-Coupling of α-Bromocarboxylic Acid Derivatives with Aryl Grignard Reagents.

✍ Scribed by Masayoshi Jin; Masaharu Nakamura

Publisher
John Wiley and Sons
Year
2012
Weight
38 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

A simple and effective method for the synthesis of the compounds (III) and (V) is presented.

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✍ Jonatan Kleimark; Per-Fredrik Larsson; Parisa Emamy; Anna Hedström; Per-Ola Norr 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 English ⚖ 441 KB 👁 2 views

## Abstract The title reaction has been studied under low temperature conditions. Coupling with active substrates can be done even at dry ice temperature. Initial rate studies at −25 °C indicate that high concentrations of any reagent can lead to either complete or partial catalyst deactivation. Un