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ChemInform Abstract: Iron-Catalyzed C—H Bond Activation for the ortho-Arylation of Aryl Pyridines and Imines with Grignard Reagents.

✍ Scribed by Naohiko Yoshikai; Sobi Asako; Takeshi Yamakawa; Laurean Ilies; Eiichi Nakamura

Publisher
John Wiley and Sons
Year
2012
Weight
49 KB
Volume
43
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Iron-Catalyzed Stereospecific Activation of Olefinic C—H Bonds with Grignard Reagent for Synthesis of Substituted Olefins.
✍ Laurean Ilies; Sobi Asako; Eiichi Nakamura 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 44 KB

## Abstract The iron‐catalyzed functionalization of acyclic or cyclic olefins which possess a directing group such as pyridine via stereospecific C—H bond activation in the presence of a mild oxidant and an aromatic cosolvent takes place in a (Z)‐specific manner.