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ChemInform Abstract: Iron-Catalyzed Aziridination Reactions.

✍ Scribed by Masafumi Nakanishi; Anne-Frederique Salit; Carsten Bolm


Publisher
John Wiley and Sons
Year
2008
Weight
50 KB
Volume
39
Category
Article
ISSN
0931-7597

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Iron-Catalyzed Aziridination Reactions
✍ Masafumi Nakanishi; Anne-Frederique Salit; Carsten Bolm πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 212 KB πŸ‘ 1 views

## Abstract A small quantity of iron(II) triflate (2.5 to 5 mol%) catalyzes the aziridination reactions of enol silyl ethers with tosylimino(iodo)benzene (PhINTs) in acetonitrile to give α‐__N__‐tosylamido ketones by subsequent aziridine ring opening. Olefins are converted into aziridines by 5 mol%