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ChemInform Abstract: Iron-Catalyzed Aminolysis of β-Carbonyl 1,3-Dithianes: Synthesis of Stereodefined β-Enaminones and 3,4-Disubstituted Pyrazoles.

✍ Scribed by Yeming Wang; Xihe Bi; Wei-Qi Li; Dehua Li; Qian Zhang; Qun Liu; Brim Stevy Ondon

Publisher
John Wiley and Sons
Year
2011
Weight
52 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The reaction of dithiane‐substituted bicarbonyl compounds with ammonia and amines (VI) or (VIII) proceeds with complete or excellent (E)‐selectivity leading to stereodefined β‐aminones.

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