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ChemInform Abstract: Iridium-Catalyzed C—H Activation versus Directed ortho-Metalation: Complementary Borylation of Aromatics and Heteroaromatics.

✍ Scribed by Eduard Hartmann; Wolfgang Kuegel; Jean-Christophe Parisienne-La Salle; Andrei S. Batsanov; Todd B. Marder; Victor Snieckus

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

Ir‐catalyzed borylation reactions are achieved on a variety of aryl and pyridyl amide and carbamate substrates.

📜 SIMILAR VOLUMES

Iridium-Catalyzed CH Activation versus D
Iridium-Catalyzed CH Activation versus Directed ortho Metalation: Complementary Borylation of Aromatics and Heteroaromatics
✍ Timothy E. Hurst; Todd K. Macklin; Maike Becker; Eduard Hartmann; Wolfgang Kügel 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 272 KB 👁 2 views

## Abstract Systematic studies are presented demonstrating the complementarity of directed __ortho__ metalation (D__o__M) and Ir‐catalyzed strategies for the provision of borylated aromatics and their subsequent Suzuki–Miyaura coupling reactions. A new concept, the use of the TMS group, readily int