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ChemInform Abstract: Iridium-Catalyzed Asymmetric Ring-Opening Reactions of N-Boc-azabenzonorbornadiene with Secondary Amine Nucleophiles.

✍ Scribed by Dingqiao Yang; Yuhua Long; Huan Wang; Zhenming Zhang

Publisher
John Wiley and Sons
Year
2009
Weight
49 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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## Abstract Asymmetric ring‐opening reactions of __N__‐Boc‐azabenzonorbornadiene with __N__‐substituted piperazine nucleophiles in the presence of 5 mol% of [Rh(COD)Cl]~2~ and 10 mol% of chiral ligand, (__R__,__S__)‐PPF‐P‐__t__‐Bu~2~, gave the corresponding 1,2‐diamine product in moderate to excell